New type of ferrocene group substituted porphyrin axial coordinate self-assembly for dye-sensitized solar cells
Liu, Hua1; Wu, Yu2; Wu, Fang-Yuan1; Liu, Jia-Cheng1
2019-08-01
发表期刊ORGANIC ELECTRONICS
ISSN1566-1199
卷号71页码:290-295
摘要In this work, three meso-substitued zinc porphyrins with different ferrocene donor units (ZnPx, x = 1–3) have been designed, synthesized, and well-characterized. The self-assemblies constructured with the zinc porphyrins and an anchor porphyrin (ZnPA) through the axial coordination linkage (Zn-to-ligand) have been applied as sensitizer in dye sensitized solar cells. Our results revealed that the self assemblies based cells showed significantly improved photocurrent conversion efficiency. Particularly, ferrocene through an amide bridge based zinc porphyrin (ZnP1) solar cell showed higher conversion efficiency compared with its derivatives. These results were also verified by electrochemical impedance spectroscopy, absorbed photon current efficiency, light harvesting efficiency and optical performance. © 2019
关键词Amides Conversion efficiency Efficiency Electrochemical impedance spectroscopy Iron compounds Organometallics Phosphorus compounds Porphyrins Self assembly Solar cells Zinc Zinc compounds Absorbed photons Axial coordinates Axial coordination Donor units Ferrocenes Light-harvesting Optical performance Zinc porphyrins
DOI10.1016/j.orgel.2019.05.042
收录类别EI ; SCIE
语种英语
WOS研究方向Materials Science ; Physics
WOS类目Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号WOS:000469838800042
出版者Elsevier B.V.
EI入藏号20192307004186
EI主题词Dye-sensitized solar cells
EI分类号525.5 Energy Conversion Issues ; 546.3 Zinc and Alloys ; 702.3 Solar Cells ; 801 Chemistry ; 804.1 Organic Compounds ; 913.1 Production Engineering ; 951 Materials Science
原始文献类型Journal article (JA)
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符https://ir.nwnu.edu.cn/handle/39RV6HYL/32856
专题科研机构_甘肃省生物电化学与环境分析重点实验室
科研机构_生态环境相关高分子材料教育部重点实验室
实体学院_化学化工学院
通讯作者Liu, Jia-Cheng
作者单位1.Northwest Normal Univ, Key Lab Bioelectrochem & Environm Anal Gansu Prov, Key Lab Ecoenvironm Related Polymer Mat, Minist Educ,Key Lab Polymer Mat Gansu Prov,Coll C, Lanzhou 730070, Gansu, Peoples R China;
2.Qiannan Normal Univ Nationalities, Sch Chem & Chem Engn, Duyun 558000, Peoples R China
第一作者单位生态环境相关高分子材料教育部重点实验室
通讯作者单位生态环境相关高分子材料教育部重点实验室
第一作者的第一单位生态环境相关高分子材料教育部重点实验室
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GB/T 7714
Liu, Hua,Wu, Yu,Wu, Fang-Yuan,et al. New type of ferrocene group substituted porphyrin axial coordinate self-assembly for dye-sensitized solar cells[J]. ORGANIC ELECTRONICS,2019,71:290-295.
APA Liu, Hua,Wu, Yu,Wu, Fang-Yuan,&Liu, Jia-Cheng.(2019).New type of ferrocene group substituted porphyrin axial coordinate self-assembly for dye-sensitized solar cells.ORGANIC ELECTRONICS,71,290-295.
MLA Liu, Hua,et al."New type of ferrocene group substituted porphyrin axial coordinate self-assembly for dye-sensitized solar cells".ORGANIC ELECTRONICS 71(2019):290-295.
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