Preparation and characterization of poly(AA-co-Fe(phen)3) self-oscillating gel

doi:10.1080/1539445X.2017.1324799

	Preparation and characterization of poly(AA-co-Fe(phen)3) self-oscillating gel
	Ren, Jie; Tao, Li; He, Jihong; Gu, Jinfen; Yang, Wu
	2017-07-03
发表期刊	SOFT MATERIALS
ISSN	1539-445X
卷号	15 期号:3 页码:222-228
摘要	A novel gel which undergoes an autonomic and periodical swelling–deswelling oscillation without any on–off switching of external stimuli was prepared by copolymerization of acrylic acid (AA) with iron (5-(acrylamide-N-yl)-1,10-phenanthroline) bis(1,10-phenanthroline) (Fe(phen)3) as the catalyst for the Belousov–Zhabotinsky (BZ) reaction. The swelling–shrinking and redox potential self-oscillating behaviors of the gels in an aqueous solution containing BZ substrates (except for the metal catalyst) were investigated. It was found that the swelling–shrinking amplitude of the gel was closely related to the content of the immobilized Fe(phen)3 catalyst. Moreover, the Turing patterns were observed first in the process of the volume self-oscillating. © 2017 Taylor & Francis Group, LLC.
关键词	Acrylic monomers Amides Ascorbic acid Catalysts Redox reactions 1 ,10-phenanthroline BZ reaction External stimulus poly(AA-co-Fe(phen)3) Redox potentials Self-oscillating Self-oscillating gel Turing patterns
DOI	10.1080/1539445X.2017.1324799
收录类别	EI
语种	英语
出版者	Taylor and Francis Inc., 325 Chestnut St, Suite 800, Philadelphia, PA 19106, United States
EI入藏号	20172403769749
EI主题词	Iron compounds
EI分类号	802.2 Chemical Reactions ; 803 Chemical Agents and Basic Industrial Chemicals ; 804 Chemical Products Generally ; 804.1 Organic Compounds
原始文献类型	Journal article (JA)
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.nwnu.edu.cn/handle/39RV6HYL/31609
专题	实体学院_化学化工学院科研机构_甘肃省生物电化学与环境分析重点实验室
通讯作者	Ren, Jie
作者单位	Chemistry & Chemical Engineering College, Northwest Normal University, Key Lab of Bioelectrochemtry & Environmental Analysis of Gansu, Lanzhou, China
第一作者单位	甘肃省生物电化学与环境分析重点实验室
通讯作者单位	甘肃省生物电化学与环境分析重点实验室
第一作者的第一单位	甘肃省生物电化学与环境分析重点实验室
推荐引用方式 GB/T 7714	Ren, Jie,Tao, Li,He, Jihong,et al. Preparation and characterization of poly(AA-co-Fe(phen)3) self-oscillating gel[J]. SOFT MATERIALS,2017,15(3):222-228.
APA	Ren, Jie,Tao, Li,He, Jihong,Gu, Jinfen,&Yang, Wu.(2017).Preparation and characterization of poly(AA-co-Fe(phen)3) self-oscillating gel.SOFT MATERIALS,15(3),222-228.
MLA	Ren, Jie,et al."Preparation and characterization of poly(AA-co-Fe(phen)3) self-oscillating gel".SOFT MATERIALS 15.3(2017):222-228.