Preparation and characterization of poly(NIPAAm-co-AMPS-co-Fe(phen)3) self-oscillating copolymers

doi:10.1007/s00396-016-3860-4

	Preparation and characterization of poly(NIPAAm-co-AMPS-co-Fe(phen)3) self-oscillating copolymers
	Ren, Jie1,2 ; Tao, Li 1; Zhang, Guangcheng 2; Yao, Mengqi 1; Gu, Jinfen 1; Yang, Wu1
	2016-06-01
发表期刊	COLLOID AND POLYMER SCIENCE
ISSN	0303-402X
卷号	294 期号:6 页码:1011-1017
摘要	A novel self-oscillating copolymer was prepared by utilizing Fe(phen)3 as the catalyst of the Belousov–Zhabotinsky (BZ) reaction. In this study, 2-acrylamido-2-methylpropane sulfonic acid (AMPS) was newly introduced into the copolymer of N-isopropylacrylamide (NIPAAm) and Fe(phen)3 as the H+providing agent for the BZ reaction. The results indicated that the copolymer solution underwent soluble–insoluble self-oscillation only in malonic acid (MA) and potassium bromate(KBrO3) mixture solution, and the amplitudes were much bigger than those of poly(NIPAAm-co-Fe(phen)3). That is to say, the novel copolymer succeeds in self-oscillating under acid-free conditions. Moreover, the oscillating characteristics were closely related to the content of AMPS in the copolymer. © 2016, Springer-Verlag Berlin Heidelberg.
关键词	Acrylic monomers Amides 2-acrylamido-2-methylpropane sulfonic acids Acid-free conditions BZ reaction Copolymer solution N-isopropylacrylamides Poly(NIPAAm-co-AMPS-co-Fe(phen)3) Self-oscillating Self-oscillations
DOI	10.1007/s00396-016-3860-4
收录类别	EI ; SCIE
语种	英语
WOS研究方向	Chemistry ; Polymer Science
WOS类目	Chemistry, Physical ; Polymer Science
WOS记录号	WOS:000376281200007
出版者	Springer Verlag
EI入藏号	20161302164110
EI主题词	Potassium compounds
EI分类号	804.1 Organic Compounds
原始文献类型	Journal article (JA)
引用统计	被引频次[WOS]：0 [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	https://ir.nwnu.edu.cn/handle/39RV6HYL/31140
专题	实体学院_化学化工学院科研机构_甘肃省生物电化学与环境分析重点实验室
通讯作者	Ren, Jie
作者单位	1.Northwest Normal Univ, Key Lab Bioelectrochem & Environm Anal Gansu, Chem & Chem Engn Coll, Lanzhou 730070, Peoples R China; 2.Northwestern Polytech Univ, Sch Nat & Appl Sci, Xian 710072, Peoples R China
第一作者单位	化学化工学院
通讯作者单位	化学化工学院
第一作者的第一单位	化学化工学院
推荐引用方式 GB/T 7714	Ren, Jie,Tao, Li,Zhang, Guangcheng,et al. Preparation and characterization of poly(NIPAAm-co-AMPS-co-Fe(phen)3) self-oscillating copolymers[J]. COLLOID AND POLYMER SCIENCE,2016,294(6):1011-1017.
APA	Ren, Jie,Tao, Li,Zhang, Guangcheng,Yao, Mengqi,Gu, Jinfen,&Yang, Wu.(2016).Preparation and characterization of poly(NIPAAm-co-AMPS-co-Fe(phen)3) self-oscillating copolymers.COLLOID AND POLYMER SCIENCE,294(6),1011-1017.
MLA	Ren, Jie,et al."Preparation and characterization of poly(NIPAAm-co-AMPS-co-Fe(phen)3) self-oscillating copolymers".COLLOID AND POLYMER SCIENCE 294.6(2016):1011-1017.

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